Solved
Enrol: Initial email to complete form
Description: We're currently aware of an issue where the initial email to complete a form from Enrol isn't being sent when Send Email Reminder isn't enabled.
The current workaround is to select Send Email Reminder before sending the form.
Our Technology team are working to resolve this as soon as possible.
Follow this post to receive updates on this issue being resolved.
I'm pleased to confirm this has now been resolved!